For every heroine and prince's love story, there must be a villainess performing dastardly deeds to keep them apart. Thus, to support the love of the dashing and noble Prince Ulysses and purehearted yet low-standing Julia, the Prince Love Support Team is formed! Their goal is to create a true underdog story and win the support of the populace for the prince and his lady.

Meliarose Maxwell is assigned the role of the haughty villainess, wielding her prestige and money over the humble Julia; Bertram Millard is the stalking horse who pines for the heroine but is destined to fail; Lynette Vicious is the villainess' lackey who bullies the heroine; and Willem Herschel is the prince's follower, acting as an informant within the inner circle. Together, the team aims to make Ulysses and Julia's budding romance shine even brighter. However, despite Meliarose zealously taking to her role, the plan keeps going astray. Does being a villainess even suit her?